The electrohydrodynamic(EHD)printing has shown broad application prospects in the field of high-performance flexible electronics,such as smart packaging,medical care,fire protection,military,etc.Compared with inkjet printing and screen printing,the EHD printing is a printing reproduction technology without contact,pressure and plate and can realize the direct digital-writing pattern on the flexible substrate.Among various flexible substrates,textiles are perfectly suitable to the development needs of wearable flexible electronic devices due to their excellent flexibility,breathability and durability.At present,the development of fabric-based the EHD printing flexible circuits is rising rapidly.When the fabric is used as aflexible substrate material,its inherent porous structure and texture characteristics will greatly affect the forming quality of EHD printing circuits.However,the current studies mostly focus on the influence of conductive ink and process parameters,and less attention has been paid to the influence of fabric substrates.Therefore,there is a lack of relevant research on the mechanism of the influence of fabric substrates on the formation and performance of the EHD printing circuits.Based on this,this work prints flexible circuits on the surface of fabrics with different densities by the EHD printing technology.To explore the influence mechanism of the formation and performance of the conductive circuits,this work analyzes the differences in wire morphology and performance,discusses their relationship with fabric characteristics,and investigates the mechanisms affecting the formability and performance of circuits on fabric surfaces.The specific research content and conclusions are as follows:(1)Forming feasibility evaluation of the EHD printing circuits on structurally differentiated fabric surfaceFirstly,the spreading behavior of conductive inks on the surface of three densities of fabrics was explored,and then the circuits were printed on the substrates of three densities under the same process conditions by the EHD printing technology.The morphology and width of the circuits was observed and measured by an optical microscope.The spreading of ink on the surface of fabrics with different structures and its effect on the circuits morphology.The results show that with the decrease of the fabric density and the increase of the roughness,the wettability of the ink on the surface of the fabric substrate increases,causing the spreading of ink faster and broader.This spreading behavior of the ink makes the line width of the EHD printed circuits on the fabric surface increase as the density of the fabric substrate decreases.Secondly,the morphologies of the single printed circuits are affected by the initial position of ink on the surface of fabric.The shape of circuits where the initial position of ink drop is located on a single yarn is better than the shape where the position is located between the gap of two yarns.In addition,compared with inkjet printing and screen printing,the accuracy of the circuit printed by EHD printing is higher.To further explore the effect of fabric substrate on printing accuracy and to meet the demand of flexible circuits for a certain width of conductive wires,further implementation of a certain width of wire printing is required.(2)Width regulation and forming evaluation of the EHD printing circuits on structurally differentiated fabric surfaceAccording to the above-mentioned rules of the spreading of ink on the fabric surface and the diffusion of ink lines,the EHD printing circuits with a certain width are realized on three kinds of commonly used cloth printing substrates with different densities by splicing multiple single lines and regulating single line spacing.Optical microscope and scanning electron microscope were used to observe the circuit morphology,including circuit width,edge uniformity and circuit thickness.The influence of fabric structure differences on its formability have been discussed.The results show that in order to obtain a circuit with a flat and uniform surface morphology,the line spacing of the fixed circuit width needs to meet the two conditions.One is without change of the width of a single line during splicing,and the other is not generating cracks.,There are two boundary value,the maximum and the minimum line spacing.As the contact angle of the fabric surface is larger and the roughness is smaller,the range of the boundary value is smaller.Besides,the printing accuracy of the obtained fixed line width circuit can be controlled by the contact angle of the ink on the fabric surface.Specifically,when the contact angle ? of the ink is in the range of 0<90°,the smaller the contact angle of the ink on the surface of the fabric,the worse the printing accuracy and thickness uniformity of the electrospray printing fixed line width circuits.Meanwhile,the optimization of the contact angle can be achieved by changing the roughness and average pore size of the fabric substrate.In addition,the formability of circuit with a certain width is better than that of single printed circuit,but there are uneven fluctuations in the edges of the circuit synchronized with the interwoven structure due to the interweaving of the warp and weft yarns in the fabric.(3)Evaluation of mechanical action resistance of the EHD printing circuits on fabric surfacesUsing the fixed line width circuits prepared on the surface of fabrics with three densities as experimental samples,the samples were subjected to bending,friction and adhesion tests with reference to relevant standards.The line resistance of the circuits before and after mechanical action was used as the evaluation index to analyze and compare the difference of mechanical action resistance of the EHD printing circuits on different fabric surfaces.Therefore,the principle of mechanical action destruction of the EHD printing circuits has been illustrated.The results show that the fabric-based EHD-printed circuit has good bending resistance.The cracks between the conductive particles(flaky nano-silver)during bending and stretching are the reasons for the increase in resistance.The greater the thickness of the circuit,the smaller the force on the conductive layer,the more difficult it is to produce cracks.At the same time,the circuit also has a certain degree of wear resistance.The damage of circuit performance is that the silver layer on the surface will fall off when rubbed,and the silver content of the conductive layer will decrease.This will cause the damage of circuit performance.Circuits with highly accuracy have better wear resistance due to smaller friction areas and stronger bonding between conductive particles.In addition,the prepared circuit does not have sufficient adhesion fastness,the failure principle is that the ink and the fabric are not protected by the extra coating.The bonding force between the fabric substrate and ink has only a physical adhesion effect,and a strong enough mechanical self-locking effect is not formed.Therefore,the adhesion performance between the two needs to be further optimized.(4)Electrical properties evaluation and application of fabric-based the EHD printing circuitsThe fixed line width circuits prepared on the surface of fabrics with three densities were used as experimental samples.The resistance and uniformity of the samples were measured with reference to relevant standards,and the influence of substrate characteristics and circuit formability on the electrical properties was discussed.Then,the fabric with the best circuit performance was selected as the substrate,and the RFID tag was prepared on its surface by the EHD printing technology and flip-package process.The antenna impedance and tag reading performance were tested to verify the feasibility of the EHD printing technology in e-textile preparation.The results show that the fabric-based EHD-printed circuits have good electrical properties.The difference in electrical properties of circuits on different fabric surfaces depends on the difference in forming.The difference in printing accuracy affects the uniformity of conduction.The difference in circuit thickness affects the square resistance and impedance.Finally,the prepared EHD-printed RFID tag meets the requirements of production application with a reading range of 8 to 12 m,so that its feasibility has been verified.In summary,this work compares the formation and performance of EHD printing conductive circuits on fabrics with different characteristics,and explains the related mechanism,which provide some practical guidance for the preparation of EHD-printed textile-based flexible circuits.In addition,the application feasibility of EHD printing in textile-based RFID tag antennas is verified,which provides a new direction for application of EHD printing technique into the fabrication of fabric-based RFID tags.In summary,this work compares the formation and performance of EHD printing conductive circuits on fabrics with different characteristics,and explains the related mechanism,which provide some practical guidance for the preparation of EHD-printed textile-based flexible circuits.In addition,the application feasibility of EHD printing in textile-based RFID tag antennas is verified,which provides a new direction for application of EHD printing technique into the fabrication of fabric-based RFID tags. |