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The Synthesis Of Star-shaped Acrylamide Polymers By Single Electron Transfer Living Radical Polymerization

Posted on:2018-06-19Degree:MasterType:Thesis
Country:ChinaCandidate:L X YangFull Text:PDF
GTID:2321330512996262Subject:Engineering
Abstract/Summary:
Acrylamide Polymer is currently the world’s most widely used type of polymer,synthesized from acrylamide and different functional monomers,and it can be used in multiple fields.Compared with Linear-shaped Acrylamide Polymers,Star-shaped Acrylamide Polymers has the advantages of good solubility,low viscosity and small hydrodynamic volume.Therefore,in this article,the Star-shaped Acrylamide Polymers were synthesized by Single Electron Transfer Living Radical Polymerization(SET-LRP),the concrete contents as follows:The Star-shaped acrylamide binary copolymer P(AM-co-NVP)was initiated by carbon tetrachloride,Catalyzed by elemental copper,and tris(N,N-dimethylaminoethyl)amine was the ligand,synthesized in aqueous solution by SET-LRP.Infrared spectrum(FT-IR)and 13C-NMR was used to analyze and characterize the structure of the product.The results showed that the acrylamide-based polymer was successfully synthesized.The Star-shaped acrylamide binary copolymer P(AM-co-AMPS)was initiated by tetrachloroethane,Catalyzed by elemental copper,and tris(N,N-dimethylaminoethyl)amine was the ligand,synthesized in aqueous solution by SET-LRP method.Infrared spectrum(FT-IR)and 13C-NMR was used to analyze and characterize the structure of the product.The results showed that the acrylamide-based polymer was successfully synthesized.The Star-shaped acrylamide terpolymer P(AM-NVP-AA)was initiated by carbon tetrachloride,Catalyzed by elemental copper,and tris(N,N-dimethylaminoethyl)amine was the ligand,synthesized in aqueous solution by SET-LRP method.Infrared spectrum(FT-IR)and13C-NMR was used to analyze and characterize the structure of the product.The results showed that the acrylamide-based polymer was successfully synthesized.The Star-shaped acrylamide terpolymer P(AM-AMPS-NVP)was initiated by carbon tetrachloride,Catalyzed by elemental copper,and tris(N,N-dimethylaminoethyl)amine was the ligand,synthesized by SET-LRP in aqueous solution polymerization.Infrared spectrum(FT-IR)and 13C-NMR was used to analyze and characterize the structure of the product.The results showed that the acrylamide-based polymer was successfully synthesized.
Keywords/Search Tags:SET-LRP, acrylic acid, N-vinyl pyrrolidone, Star-shaped Acrylamide Polymers
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