| Ten coordination polymers have been synthesized by the reaction of Fe（Ⅱ/Ⅲ） and Cu（I/Ⅱ）ion under hydrothermal conditions. The formulas of coordination polymers are listed asfollows:[i] Fe（Ⅱ/Ⅲ）配合物（1）～（5）[ii] Cu（I/Ⅱ）配合物（6）～（10）（1）{[FeⅡFe2Ⅲ（phen）4（μ-CN）2（CN）6]·4H2O}（6）[Cu3ICuⅡ（CN）5（H2O）5]n（2）{[FeⅢ（CN）6]2·[FeⅢ（phen）3]2·phen·8H2O}（7）{[Cu2Ⅱ（Hbtc）2（H2O）6]·H2O·ppz}n（3）{[FeⅡ（Hpdc）2（H2O）2]·2H2O}（8）{Na2[Cu2Ⅱ（btec）1.5（H2O）5]·H2O}n（4）[FeⅡ（CN）6]·[FeⅡ（bipy）3]2·C2H5OH·6H2O}（9）{CuⅡ（cyan）2（H2O）2}（5）{[FeⅢ（CN）Ⅲ6]·[Fe（bipy）3]·3H2O}（10）[CuⅡ（pdc）2]·2CH3CH2OH（bipy=2,2’-bipyridine, phen=10-phenanthroline, H2pdc=2,5-pyridine-dicarboxylic acid, cyan=Cyanuric acid, H3btc=benzene-1,3,5-tricarboxylic acid, H4btec=1,2,4,5-benzenetetra-carboxylic acid, ppz=piperazine）The structural analyse indicate that: Five iron coordination complexes, the complex（1） ismixed valence Fe（Ⅱ/Ⅲ） complex, the complexes （2） and （5） are Fe（Ⅱ） complexes, thecomplexes （3） and （4） are Fe（Ⅲ） complexes. Five copper coordination complexes, thecomplex（6） is mixed valence Cu（I/Ⅱ） complex, the complexes （7） and （8） are Cu（Ⅱ）Coordination polymers, the complexes （9） and （10） are mononuclear Cu（Ⅱ） supramolecularcomplexes.All the coordination polymers are characterized by IR, UV-Vis-NIR, surfacephotovoltage spectrum and field-induced surface photovoltage spectrum which are allcompared and assigened. The surface electron behaviors of polymers under light-inducementwere studied by SPS, which were also associated with the UV-Vis absotption spectra. Theresults are presented as follows:[1] The photo-electric properties of polymers were determined and comparativelyanalized. We found that there are obvious response bands in the range of300800nm underUV-Vis light-inducement indicating the photo-electric conversion signals were generated bythe light-inducement, which reveal that ten polymers possess photo-electric conversionproperties. [2] There are good corresponding relationships beteen SPS and UV-Vis absorptionspectra.[3] The influences of valence of central metal Fe ions to the number of SPS. Forexample, Complexes（1）-（5）, The valence of central metal Fe ions are different, makes thenumber of SPS are different. mixed valence complexes makes SPS in several splitting.[4] The number of central meta ions of Asymmetric unit, to the SPS are different. Forexample, Complexes（6）-（10）, The number of central meta Cu ions of Asymmetric unit aredifferent, makes the number of SPS are different. The intensity of SPS are different. |
PDF Full Text Request