Synthesis, Properties And Structural Chemistry Of Nitrogen Heterocyclic Ring Directed Lead, Silver, Copper Coordination Polymer

Coordination polymer is composed of transition metal and organtic ligands.It is the same to neither inorganic polymer nor general compound high polymer .But it linked the merit of these material. and represented many unique quality.Such as various structure, special electric effect and available transition element. Many other intrinsic value are been intresented in scientific and industrial field.The coordination polymer of azotic heteroatomic ring are generally obtained by the reactin of pyridine and its derivant and the salt of transition element. Because the organic ligand of azotic heteroatomic ring is a great variety, the multiple coordination polymers have novel structure and unique feature,which had been synthesized.Such as good catalytic effect, powerful magnetic performance , good nonlinear potical property and so on.We used the derivant of quinoline and morpholine as the ligand and synthesized seven coordination polymer. Also we employed X-ray single crystal diffractometer technology to determine their structures. The IR spectrums of the compounds have been characterized. UV-Vis spectrums of all compounds have been characterized and attributed. The three nonlinear potical property was employed of partial compounds.The compounds that have been synthesised and determine their structures:[(C₁₃H₁₆N)(PbI₃)]_n Compound 1[(C₂₆H₂₆N₂)(Cu₂I₄)]_n Compound 2[(C₂₈H₃₆N₂)(Cu₅I₇)]_n Compound 3[(C₃₀H₄₃N₃)(DMF)(Pb₃I₉)]_n Compound 4[(C₅₆H₇₀)N₄](Ag₄I₈)]_n Compound 5[(C₁₀H₂₀N₂O₂)₂(Ag₂I₄)]_n Compound 6[(C₈H₁₇NO)₃(Pb₆I₁₈)]_n Compound 7...