| he microstructure, microchemistry and thermoelectric properties of three types of thermoelectric materials have been studied in this research. They include conventional ball milled and hot sintered n-type ;Secondly, a fine grain structure containing microtwins of number density ;The third experimental investigation is on the variation of microstructure and thermoelectric properties of arc melted TiNiSn alloys with annealing at 800;Finally, a calculation has been performed based on Klemens-Callaway relaxation time theory to elucidate the effect of grain size and second phase particles on thermal conductivity (;First, it was found that the grain size of the annealed n-type alloys is very uniform, with the average diameter about 60... |