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Preparation and characterization of bi-metallic nanoparticle catalyst having better anti-coking properties using reverse micelle technique

Posted on:2013-10-13Degree:M.E.SType:Thesis
University:Lamar University - BeaumontCandidate:Zacharia, ThomasFull Text:PDF
GTID:2451390008973525Subject:Engineering
Abstract/Summary:
Energy needs are rising on an exponential basis. The mammoth energy sources like coal, natural gas and petroleum are the cause of pollution. The large outcry for an alternate energy source which is environmentally friendly and energy efficient is heard during the past few years. This is where "Clean-Fuel" like hydrogen gained its ground. Hydrogen is mainly produced by steam methane reforming (SMR). An alternate sustainable process which can reduce the cost as well as eliminate the waste products is Tri-reforming. In both these reforming processes nickel is used as catalyst. However as the process goes on the catalyst gets deactivated due to coking on the catalytic surface.;This goal of this thesis work was to develop a bi-metallic catalyst which has better anti-coking properties compared to the conventional nickel catalyst. Tin was used to dope nickel. It was found that Ni3Sn complex around a core of Ni is coking resistant compared to pure nickel catalyst. Reverse micelle synthesis of catalyst preparation was used to control the size and shape of catalytic particles. These studies will benefit researches on hydrogen production and catalyst manufactures who work on different bi-metallic combinations...
Keywords/Search Tags:Catalyst, Bi-metallic
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