| This thesis focuses on the thermal plasma treatment of non-point source pollutants accumulating in stormwater ponds. Stormwater ponds are constructed as a part of urban non-point source pollution control systems. Pollutants from various sources are collected in the stormwater ponds as sediments. In this work, stormwater sediments were first separated by a filter with an opening of 208mum. The filtered sludge-water was subjected to pulsed arc electrohydraulic discharge (PAED) treatment while the solid part (i.e., wet sludge and dried PAED treated sludge) was subjected to thermal plasma treatment under non-DC transferred and partial transferred operation modes. The results from the PAED sludge-water treatment show that the reduction of TOC in sludge-water was approximately 80% and was greater than 90%, respectively, after 5 minutes and 2 hours of PAED treatment. The accumulated gaseous concentrations of C xHy, CO, CO2, SO2, H2S and NO emission from sludge-water treatment were 8.2, 3.1, 1.9, 0.32, 0.29 and 0.07 mg/L, respectively, after 2 hours of PAED treatment. The concentrations of volatile elements in sediments such as S, Br, Cl and K decreased approximately 80, 90, 30 and 20% respectively. The solid-phase carbon was observed to be approximately completely removed after treatment. Based on the above results, it can be concluded that PAED successfully degraded organic compounds into CO2, CO and CxHy, and converted sulfur and nitrate compounds into SO2, H2S and NO.;Thermal plasma wet-sludge treatments showed that a reduction of TOC was approximately 52% with argon plasma gas and air flow rates (in the reaction zone) of 24 and 2.4 L/min, respectively. Based on SEM images, wet sludge was melted under partial transferred mode. Thirteen elements with concentration relationships of O > Si > Al > Ca > S > Fe > K > Mg > Na > Cu > C > Ti > Cl were quantified by the X-ray energy dispersion technique. The elemental weight percentages of Si, K, Fe and O increased with increasing reaction zone air flow rate, while Ca and Cu decreased with increasing air flow rate. Thirty two elements were quantified by Neutron Activation Analyses (NAA) but only 27 elements were above the detection limits. Major elements (concentration > 1000 ppm) with relative concentrations of Ca > Al > Fe > K > Mg > Na > Ti > Cl; minor elements (100 - 1000 ppm) with relative concentrations of Mn > Ba > Sr > Zn; and trace elements ( V > Cr > Br > La > As > Sc > Th> As > Co > Dy > W > Sb > Eu; were determined. Concentrations of Zn, La and Co were enriched 90, 50 and 30% on average respectively, while concentrations of Br, W and As decreased by 80, 50 and 20% on average respectively. The chemical compositions in sludge were quite different after thermal plasma treatment. The average percentages of sand (SiO2) and calcite (CaCO3) decreased 35 and 10% respectively, while compounds such as KAlSi3O8, Fe 3O4, NaCl and CaSO4 were formed after thermal plasma treatment. Gaseous hydrocarbons, H2S, CO and NO were emitted continuously during the thermal plasma treatment of sludge. Higher reduction of organics and sulfur compounds and suppression of NOx formation were observed in the thermal plasma treatment of wet sludge. The integrated system consisting of PAED sludge-water treatment and thermal plasma wet sludge treatment under partial transferred mode may provide a potential for stormwater pond sediment treatment control. |
