Synthesis、Characterization And Properties Of The Series Coordination Polymers Based On Divalent Metal

Coordination polymer as a new type of functional materials with rich topology structure and the accumulation of diverse ways,the adsorption material,molecular recognition,magnetic materials and optical materials showed a broad application prospect,become the research focus in the material chemistry and coordination chemistry.In this paper,ten complexes have been hydrothermally synthesized through hydrothermal technology with three new ligands（L1: 11-fluoro-dipyrido[3,2-a:2′,3′-c] phenazine;L²: 2-（4-fluorophenyl）-1H-imidazo[4,5-f][1,10] phenanthroline;L³: 2-（2-chloro-6-fluorophenyl）-1H-imidazo[4,5-f][1,10]phenanthroline）phenanthroline,organic carboxylic acid and metal ions.And these complexes are characterized by X-ray,IR spectrum,element analysis,thermo gravimetry analysis and fluorescent spectroscopy.[Cd（bpdc）（L1）₂]·3H₂O（1）[Cd（Cl）₂（L²）（H₂O）]2（2）[Cd₂（Cl）（1,3-BDC）1.5（L³）₂]·1.25H₂O（3）[Cd（1,4-NDC）（L³）]（4）[Cd（H₂biim）₂（SO₄）]n·3nH₂O（5）[Cd（L⁴）（bipy）₂]n（6）[Cd（CNA）]n（7）[Sr（L⁴）（phen）（H₂O）]（8）[Pb（L⁵）]（9）[Cu₂（L⁶）（1,3-BDC）]n（10）...