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Laser Remanufacturing And Zinc Corrosion Mechanism Of Sink Roll Sleeve

Posted on:2016-08-01Degree:MasterType:Thesis
Country:ChinaCandidate:J LiuFull Text:PDF
GTID:2181330467989659Subject:Materials science
Abstract/Summary:PDF Full Text Request
Due to the limitations of steel materials resistant to molten zinc corrosion, liquid zinccorrosion of the sink roll and sleeve material is often restricted continuous hot-dip galvanizingan important part of normal production. Sink roll material widely used at home and abroadSUS-316L stainless steel. Therefore, this topic uses laser cladding technology by optimizingthe process parameters and alloy powder composition ratio,316L stainless steel surface wasprepared in good shape, excellent performance of Co-based alloys modified layer, anddeveloped rare earth oxide, Si and Cr、W、B alloying elements can affect organizationalstructure, high temperature wear properties and liquid zinc corrosion resistance of theCo-based alloy laser cladding layer, investigated the corrosion mechanism of the modifiedlayer in molten zinc and explored new molten zinc resistant surface coating materials.The results showed that: the organization of Co-based alloy laser cladding of0.5%CeO2was more dense, dendrite was relatively small, the secondary dendrite spacing was small, goodformability cladding layer. With the increase of Si, Laves phase of Co-based alloy lasercladding layer increased, hardness, high temperature wear properties improved, liquid zinccorrosion resistance capacity enhanced. In addition, after adding elements Cr, distribution ofLaves phase of Co-based alloy laser cladding was more uniform, after adding W and Belements, Co-based alloy laser cladding appeared separately a new wear-resistant hard phaseCo6W6C and CrB, laid the theoretical foundation for the further study of Co-based alloyshigh-quality laser cladding.Through morphology observation and analysis of the molten zinc solution of Co-basedalloy laser cladding, proposed molten zinc corrosion model and molten zinc corrosionmechanism of Co-based alloy laser cladding layer. Molten zinc corrosion of Co-based alloylaser cladding layer was mainly formed by Co-Zn compounds, to keep the Co-based solidsolution corrosion consumption. Molten zinc corrosion resistance of Co-based alloy lasercladding of0.5%CeO2was strong. Molten zinc corrosion process of Co-based alloy lasercladding of Si and Cr, W, B alloying elements could be simply stated as, transition Co-basedsolid solution matrix was preferentially corrode, eventually leading to be wrapped cover theLaves phase exfoliation, forming a typical tissue-selective corrosion. The study foundCo-based alloy laser cladding of adding Cr、W alloying elements evenly distributed molten zinc corrosion resistance of a large number of small Laves phase and wear hard phase Co6W6C,the best overall performance.
Keywords/Search Tags:Co-based alloys, Rare earth, Laves phase, Molten zinc, Corrosion mechanism, Friction and wear
PDF Full Text Request
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