Synthesis And Property Study Of Inorganic-organic Compound On The Basis Of Ag And Ligand Containing NSO

In recent years,a great deal of effort has been devoted to the design and assembly of supramolecular compounds,for these compounds have potential applications in the ionophore chemistry,ion pair extraction chemistry,phase transfer catalysis chemistry and so on.In particular,the hydrogen bonding has attracted most interest due to its relative strength and directionality in generating a great variety of one-(1-D),two-(2-D),and three-dimensional(3-D) either non-interpenerating open networks with variable cavities or channels of desire size,or well entangled structures through interpeneration.In this paper,we synthesize a new complex,{[Ag₂(bpy)₂]²⁺[Ag₂(KMW)₂]^2-}_n,used bpy and kmw by conventional method.The study on synthetic conditions and rules for the new compound is carried out and the structure is characterized by elemental analyses,IR,TG,and single crystal X-ray diffractions.