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Preparation And Properties Of One-Dimensional Inorganic Materials

Posted on:2009-10-29Degree:MasterType:Thesis
Country:ChinaCandidate:Y XiaoFull Text:PDF
GTID:2121360272478821Subject:Materials science
Abstract/Summary:PDF Full Text Request
One-dimensional or normal one-dimensional structure inorganic nanomaterials have potential application in electronics,photonics,mechanics areas and so on. The nanofibers have been attracted by many researchers and have become the hot study of nano-technology due to their superior optical, acoustic, electrical, magnetic, thermal and mechanical properties. The illuminant rare-earth oxide materials have been widely used in high-tech fields. The study of preparation, properties, and application of the rare-earth oxide nanofibers have become an important subject. In recent years, the electrospining combined with sol-gel is a relatively convenient and useful way to fabrication inorganic nanofibers. Against the back ground of preparation and application of one-dimensional nanomaterials, the article reports on the latest progress in research of one-dimensional naonomaterials and our research achievements with the emphasis of preparing one-dimensional nanomaterials. The contents are as follows:1. The TiO2-ZrO2 complex nanotubes were prepared by sol-gel coating of electrospining polymer fibers. PBS nanofibers were used as substrate, PBS-TiO2-ZrO2 coaxial nanofibers were fabricated using sol-gel coating technique to fill PBS nanofibers that were prepared by electrospining. The TiO2-ZrO2 complex nanotubes were obtained via calcining PBS-TiO2-ZrO2 coaxial nanofibers. SEM,TEM and TG techniques were performed to the nanotubes.2. The inorganic BaO-TiO2 nanofibers have been fabricated by sol-gel combined with electrospining method. PVP was used as substrate, ethanol was used as solvent, while barium acetate and Tetra-n-butyl titanate were used as precursor. The PVP/Ba(CH3COO)2/TiO2 composite nanofibers were fabricated by electrospining. The inorganic BaO-TiO2 nanofibers were obtained via calcining PVP/Ba(CH3COO)2/TiO2 composite nanofibers. TG, SEM, IR, and XRD techniques were performed to the organic and inorganic nanofibers.3. The inorganic Mn doped ZnO nanofibers have been fabricated by sol-gel combined with electrospining method. PVP was used as substrate, ethanol was used as solvent while Mn(CH3COO)2 and Zn(CH3COO)2 was used as precursor. The PVP/Mn(CH3COO)2/Zn(CH3COO)2 composite nanofibers were fabricated by electrospining. The inorganic Mn doped ZnO nanofibers were obtained via calcining PVP/Mn(CH3COO)2/Zn(CH3COO)2 composite nanofibers. TG, SEM, IR, XRD and Fluorescence spectrometer techniques were performed to the organic and inorganic fibers. The XRD indicated that the production structure was ZnMn2O4 crystalline.4. The inorganic La2O3 nanofibers have been fabricated by sol-gel combined with electrospining method. PVP was used as substrate, ethanol was used as solvent while LaAC3 was used as precursor. The PVP/LaAC3 composite nanofibers were fabricated by electrospining. The inorganic La2O3 nanofibers were obtained via calcining PVP/LaAC3 composite nanofibers. TG, SEM, IR, XRD and Fluorescence spectrometer techniques were performed to the organic and inorganic fibers.
Keywords/Search Tags:electrospinning, sol-gel, inorganic nanofiber, nanotubes
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