Studies On Characterization And Synthesis Of Fatty Amine Polyoxyethylene Ethers Antistatic Agents By SO₄～(2-)/ZrO₂ Superacid Catalyst

SO₄^2-/ZrO₂ solid superacid catalyst was prepared in different concentrations and different calcination temperatures. The surface acidity of SO₄^2-/ZrO₂ superacid catalyst was determined by FT-IR, DSC and XRD. The following information attained. When calcination temperature was not very high, there were not only lewis acidic sites but also Bronsted acidic sites on the surface of catalysts. With the calcination temperature getting high, the Bronsted acidic sites increased. Both H₂SO₄ concentration and calcination temperature are important influence factors for the acidity distribution of catalyst. When H₂SO₄ was 1mol·dm^-3 or calcination temperature was 550℃, the stronger acidic sites on the catalytic surface were the most abundance. The stability of active sites on ZrO₂ was in the following order: amorphous ZrO₂>tetragonal ZrO₂>monoclinic ZrO₂.A plastics-use non-ionic antistatic agent was synthesized from lurylamine / n-octadecy amine and ethylene oxide. The effect of the kind and the dosage of...