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Intramolecular Nucleophilic Addition Of Vinylpalladiums To 1-(2-bromophenyl) Alcohol

Posted on:2006-08-06Degree:MasterType:Thesis
Country:ChinaCandidate:S F WangFull Text:PDF
GTID:2121360155976066Subject:Organic Chemistry
Abstract/Summary:PDF Full Text Request
1,4-diphenyl-2,3-dipropylclopenta-2,4-dienol(A), 1,2,3,4-tetraphenylcyclopenta-2,4-dienol(B),2,3-dipropyl-4,5,6,7-tetrahydro-1H-inden-1-ol(C),2,3-diphenyl-4,5,6,7- tetrahydro-1H-inden-1-ol(D),1-phenyl-2,3-dipropyl-4,5,6,7,-tetrahydro-1H-inden-1-ol (E),1,2,3,-triphenyl-4,5,6,7-tetrahydro-1H-inden-1-ol(F),1-methyl-2,3-dipropyl-1H-inden-1-ol(G),1-methyl-2,3-diphenyl-1H-inden-1-ol(H),1-ethyl-2,3-dipropyl-1H-inden-1-ol(I),1-ethyl-2,3-diphenyl-1H-inden-1-ol(J),1 -phenyl-2,3-dipropyl-1H-inden-1-ol( K),1,2,3-triphenyl-1H-inden-1-ol(L),1-phenyl-2,3-dihydro-1H-inden-1-ol(M),1-phen yl-1H-inden-1-ol(N),1-hydroxy-1-phenyl-1H-inden-2-yl)(phenyl)methanone(O) were designed on the basis of the predecessors' research on intramolecular nucleophilic addition of vinylpalladiums and arylpalladiums to ketones. The compounds G,H,I,K and L were synthesized via "one-pot" method. Compound I and J were new compounds and the structures of them were determined by IR, 1H-NMR, 13C-NMR, MS.The aim compounds were not got during the synthesis of other compoundsA, B, C, D, E, F, M, N, O, P. The causes of defeated were explored.
Keywords/Search Tags:intramolecular nucleophilic addition, vinylpalladiums, arylpalladiums, "one-pot" method
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