Modeling and optimization of a concentrated solar supercritical CO2 power plant

Renewable energy sources are fundamental alternatives to supply the rising energy demand in the world and to reduce or replace fossil fuel technologies. In order to make renewable-based technologies suitable for commercial and industrial applications, two main challenges need to be solved: the design and manufacture of highly efficient devices and reliable systems to operate under intermittent energy supply conditions. In particular, power generation technologies based on solar energy are one of the most promising alternatives to supply the world energy demand and reduce the dependence on fossil fuel technologies. In this dissertation, the dynamic behavior of a Concentrated Solar Power (CSP) supercritical CO2 cycle is studied under different seasonal conditions. The system analyzed is composed of a central receiver, hot and cold thermal energy storage units, a heat exchanger, a recuperator, and multi-stage compression-expansion subsystems with intercoolers and reheaters between compressors and turbines respectively. The effects of operating and design parameters on the system performance are analyzed. Some of these parameters are the mass flow rate, intermediate pressures, number of compression-expansion stages, heat exchangers' effectiveness, multi-tank thermal energy storage, overall heat transfer coefficient between the solar receiver and the environment and the effective area of the recuperator. Energy and exergy models for each component of the system are developed to optimize operating parameters in order to lead to maximum efficiency. From the exergy analysis, the components with high contribution to exergy destruction were identified. These components, which represent an important potential of improvement, are the recuperator, the hot thermal energy storage tank and the solar receiver. Two complementary alternatives to improve the efficiency of concentrated solar thermal systems are proposed in this dissertation: the optimization of the system's operating parameters and optimization of less efficient components. The parametric optimization is developed for a 1MW reference CSP system with CO2 as the working fluid. The component optimization, focused on the less efficient components, comprises some design modifications to the traditional component configuration for the recuperator, the hot thermal energy storage tank and the solar receiver. The proposed optimization alternatives include the heat exchanger's effectiveness enhancement by optimizing fins shapes, multi-tank thermal energy storage configurations for the hot thermal energy storage tank and the incorporation of a transparent insulation material into the solar receiver. Some of the optimizations are conducted in a generalized way, using dimensionless models to be applicable no only to the CSP but also to other thermal systems. This project is therefore an effort to improve the efficiency of power generation systems based on solar energy in order to make them competitive with conventional fossil fuel power generation devices. The results show that the parametric optimization leads the system to an efficiency of about 21% and a maximum power output close to 1.5 MW. The process efficiencies obtained in this work, of more than 21%, are relatively good for a solar-thermal conversion system and are also comparable with efficiencies of conversion of high performance PV panels. The thermal energy storage allows the system to operate for several hours after sunset. This operating time is approximately increased from 220 to 480 minutes after optimization. The hot and cold thermal energy storage also lessens the temperature fluctuations by providing smooth changes of temperatures at the turbines' and compressors' inlets. Additional improvements in the overall system efficiency are possible by optimizing the less efficient components. In particular, the fin's effectiveness can be improved in more than 5% after its shape is optimized, increments in the efficiency of the thermal energy storage of about 5.7% are possible when the mass is divided into four tanks, and solar receiver efficiencies up to 70% can be maintained for high operating temperatures (~ 1200°C) when a transparent insulation material is incorporated to the receiver. The results obtained in this dissertation indicate that concentrated solar systems using supercritical CO2 could be a viable alternative to satisfying energy needs in desert areas with scarce water and fossil fuel resources.