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Determination of the symmetry of the pair function in superconducting yttrium barium copper oxide

Posted on:1991-10-29Degree:Ph.DType:Dissertation
University:Stanford UniversityCandidate:Yee, Gordon TrentFull Text:PDF
GTID:1472390017450718Subject:Chemistry
Abstract/Summary:
Although quite remarkable, the phenomenon of superconductivity is widespread, occurring in roughly half of the metallic elements, thousands of alloys, and even several purely organic charge transfer salts. It is characterized by a zero resistance state, hence its manifestation in a closed ring allows an electric current established in the ring to persist indefinitely. Yet, until recently, the highest critical temperature, T{dollar}sb{lcub}rm c{rcub}{dollar}, below which superconductivity appeared was roughly 20K.; Within the framework of the prevailing theory, it was generally believed that the highest observable critical temperature was in the range of 30-40K. The recent (1987) discovery of superconductivity in a series of cuprate ceramics near 100K, has forced a reconsideration of this long-held idea. Despite efforts over the last three years to understand these materials, the experimental and theoretical picture is still far from clear.; In this dissertation, we describe experiments which we believe demonstrate a fundamental similarity between the conventional superconductor, lead, and one of the high T{dollar}sb{lcub}rm c{rcub}{dollar} materials, YBa{dollar}sb2{dollar}Cu{dollar}sb3{dollar}O{dollar}sb7{dollar}, (YBCO). These experiments involve the study of a composite ring of the two materials. This ring consists of a single strip of lead attached to opposite sides of a sample of YBCO such that current carried in the ring must cross two junctions during each circuit of the loop. At liquid helium temperature, 4K, each material alone is superconducting, but to establish a persistent current it is necessary for the local regions around the junctions to be superconducting as well, hence the two materials must be, in some sense, compatible. We argue that establishment of a persistent current in this ring and the observation of no measurable suppression of T{dollar}sb{lcub}rm c{rcub}{dollar}, below that of lead, implies that the pair functions, which govern the superconducting properties in each material, are of the same symmetry.
Keywords/Search Tags:Superconducting, Ring
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