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CATALYTIC HYDROGENATIONS AND HYDROFORMYLATIONS USING TRANSITION METAL CLUSTERS AND POLYMER-BOUND RUTHENIUM COMPLEXES

Posted on:1981-02-03Degree:Ph.DType:Dissertation
University:The University of AlabamaCandidate:WILEMON, GARY MICHAELFull Text:PDF
GTID:1471390017966205Subject:Chemistry
Abstract/Summary:
Selective hydrogenations of 1,5-cyclooctadiene were effected using polymer-anchored RuCl(,2)(CO)(,2)(PPh(,3))(,2) in the presence of excess polymer-bound triphenylphosphine. Products obtained were cyclooctene and cyclooctane. Resin catalysts were prepared with a wide range of phosphine loading...
Keywords/Search Tags:Polymer-bound, Hydrogenations
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