Transport and structure in fuel cell proton exchange membranes

Transport properties of novel sulfonated wholly aromatic copolymers and the state-of-the-art poly(perfluorosulfonic acid) copolymer membrane for fuel cells, Nafion, were compared. Species transport (protons, methanol, water) in hydrated membranes was found to correspond with the water-self diffusion coefficient as measured by pulsed field gradient nuclear magnetic resonance (PFG NMR), which was used as a measure of the state of absorbed water in the membrane. Generally, transport properties decreased in the order Nafion > sulfonated poly(arylene ether sulfone) > sulfonated poly(imide). The water diffusion coefficients as measured by PFG NMR decreased in a similar fashion indicating that more tightly bound water existed in the sulfonated poly(arylene ether sulfone) (BPSH) and sulfonated poly(imide) (sPI) copolymers than in Nafion.; Electro-osmotic drag coefficient (ED number of water molecules conducted through the membrane per proton) studies confirmed that the water in sulfonated wholly aromatic systems is more tightly bound within the copolymer morphology. Nafion, with a water uptake of 19 wt % (lambda = 12, where lambda = N H2O/SO3H) had an electro-osmotic drag coefficient of 3.6 at 60°C, while BPSH 35 had an electro-osmotic drag coefficient of 1.2 and a water uptake of 40 wt % (lambda = 15) under the same conditions.; Addition of phosphotungstic acid decreased the total amount of water uptake in BPSH/inorganic composite membranes, but increased the fraction of loosely bound water. Zirconium hydrogen phosphate/BPSH hybrids also showed decreased bulk water uptake, but contrary to the results with phosphotungstic acid, the fraction of loosely bound water was decreased. This dissimilar behavior is attributed to the interaction of phosphotungstic acid with the sulfonic acid groups of the copolymer thereby creating loosely bound water. No such interaction exists in the zirconium hydrogen phosphate materials. The transport properties in these materials were found to correspond with the water-self diffusion coefficients.; Proton exchange membrane (PEM) transport properties were also found to be a function of the molecular weight of sulfonated poly(arylene thioether sulfone) (PATS). Low molecular weight (IV ∼ 0.69) copolymers absorbed more water on the same ion exchange capacity basis than the high molecular weight copolymers (IV ∼ 1.16). Surprisingly, protonic conductivity of the two series was similar. Moreover, the methanol permeability of the low molecular weight copolymers was increased, resulting in lower membrane selectivity and decreased mechanical properties. (Abstract shortened by UMI.)...