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Absorption spectroscopy of oxygen, carbon dioxide and water species for applications in combustion diagnostics

Posted on:2007-01-16Degree:Eng.DType:Dissertation
University:Lamar University - BeaumontCandidate:Mei, AnhuaFull Text:PDF
GTID:1441390005465947Subject:Engineering
Abstract/Summary:
Laser absorption spectroscopy has been a useful tool applied in combustion diagnostics because of its capability to measure the species' concentration, particularly to measure concentration, temperature, and pressure simultaneously. These measurements provide the necessary information for dynamic combustion control. Due to its advantages such as fast response, non-intrusive nature and applicability under harsh environment like high temperature and high pressure, absorption laser spectroscopy makes it possible to monitor combustion system on-line and in situ. Since its development for more than thirty years, laser spectroscopy has matured, and the novel and advanced laser sensors have pushed it to be applied fast. On the other hand, industry still needs cheaper and more operable spectroscopy, which becomes an important consideration in the development and application of modern laser spectroscopy. This study presents an instrumental structure including the algorithm of the spectrum computation and the hardware configuration.; The algorithm applied the central maximum value of the spectrum to simplify the computation. The whole calculation was done extensively using Beer-Lambert theory and HITRAN database which makes it efficient and applicable. This research conducted the simulations of high temperature species, such as CO2, H2O to carry out the algorithm, which were compared with published data. Also, this research designed and performed the experiments of measuring oxygen and its mixture with Helium by using a 760 nm diode laser and a 655 nm Helium/Neon laser sensor with fixed wavelength structures.; The results of this research also conclude the following: (1) extensive literature survey, field research and laboratory work; (2) studying the significant theories and experimental methods of the laser spectroscopy; (3) developing efficient and simplified algorithm for spectrum calculation; (4) simulating high temperature species H2O and CO2; (5) designing and building experiments for measuring species O2; (6) Numerical model of Abel Transform and analytical model for spatial distribution of concentration using line of sight data.; The work in this research for the spectroscopy of H2O, CO 2 and O2 will help to construct an economic, operable and robust instrument.
Keywords/Search Tags:Spectroscopy, Species, Combustion, Absorption, Laser, H2O
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