| In this work, two distinct types of Diffractive Optical Elements (DOEs) are designed to laterally distribute the solar spectrum across multiple photovoltaic (PV) cells. Each PV cell receives a spectral band near its bandgap energy to maximize overall solar-to-electric conversion efficiency of the system.;The first DOE is an off-axis volume holographic lens. Design parameters include lateral grating period and slant angle, index modulation, film thickness, and control of swelling and index modulation attenuation in the film development process. Diffraction efficiency across the holographic lens is simulated using Rigorous Coupled Wave Analysis (RCWA). A full system model is created, and non-sequential ray tracing is performed. Performance is evaluated under AM 1.5 conditions and annual insolation in Tucson, AZ, and Seattle, WA. A proof-of-concept off-axis holographic lens is fabricated and its performance is measured to confirm the optical properties of this system.;The second DOE is an algorithmically-designed freeform surface relief structure. The Gerchberg-Saxton design algorithm is expanded to consider multiple wavelengths, resulting in a Broadband Gerchberg-Saxton (BGS) algorithm. All design variables are evaluated in a parametric study of the algorithm. Several DOE designs are proposed for spectrum splitting, and two of these designs are fabricated and measured. Additional considerations, such as finite sampling of the discrete Fourier transform, fabrication error, and solar divergence are addressed.;The dissertation will conclude with a summary of spectrum splitting performance of all proposed DOEs, as well as a comparison to ideal spectrum splitting performance and discussion of areas for improvement and future work. |
