Landfill leachate, produced in the process of sanitary landfill disposal, contains high concentration of pollutants and great variation is often observed in both water quality and quantity. So it is a difficult problem in worldwide field of wastewater treatment. This study was conducted to develop an effective process for landfill leachate treatment; therefore a full-scale test using biochemical-physicochemical process and a pilot-scale test using membrane bioreactor-nanofiltration process were carried out on Laohukeng landfill site, Baoan district of Shenzhen city. Experimental results show:( 1) Biochemical-physicochemical process was used to treat Laohukeng landfill leachate in a full scale. 81.3-90.8% of COD and 63.4-75.4% of NH3-N were removed when raw leachate contained 4888-8365 mg-COD/1 and 1239-1683 mg-NH3-N/l and the HRT was kept at 49.9-68.7 h. The effluent can meet to the third discharge limit of landfill leachate(COD< 1000mg/L, NH3-N unlimited).(2) Membrane bioreactor-nanofiltration process was used to treat Laohukeng landfill leachate in a pilot scale. When raw leachate contained 10900-13000 mg-COD/1 and 2330-2910 mg-NH3-N/l, 99.4-99.8% of COD and 99.7-99.9% of NH3-N was removed at the temperature of 29-32 ℃, pH of 6.7-7.2, organic loading rate of 0.10-0.17 kgCOD/(kgMLSSd), ammonium-N loading rate of 0.02-0.04kgNH3-N/(kg-MLSS·d), recycling ratio of 9.5-25.1. The effluent can stably meet to the first discharge limit of landfill leachate(COD<100mg/L, NH3-N< 15mg/L).(3) By the discussion of technique and economy, it is sure that membrane bioreactor-nanofiltration process with many advantages in efficiency, stability, area, autocontrol, operation, and economy is a new-style technology suitable for the treatment of Laohukeng landfill leachate.In summary, this study solves the difficult problem of Laohukeng landfill leachate treatment successfully. Membrane bioreactor-nanofiltration process has instructional function and practical value, and it could be used to treat leachates similar to Laohukeng landfill site.
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